Let $k$ be an algebraically closed field of arbitrary characteristic. Let $H$ be a Hopf algebra over $k$. We say $x\in H$ is a primitive element if $\Delta(x)=1\otimes x+x\otimes 1$, where $\Delta$ is the comultiplication in $H$. The set of primitive elements in $H$, denoted $P(H)$, is a Lie subalgebra, with bracket given by the commutator.
Is $P(H)$ always nontrivial? If not, what is an example of a Hopf algebra with $P(H)=0$? What if I require $H$ to be finite-dimensional, or finite-dimensional and local? Do we have examples of such Hopf algebras with no nontrivial primitive elements?
The answer is no, even when the algebra is finite dimensional. Consider $k = \mathbb C$, and let $H = \mathbb C$ with the usual algebra structure and the comultiplication given by $\Delta(1) = 1 \otimes 1$, hence $\Delta(z) = z (1 \otimes 1)$. The counit is the identity. Then $\mathbb C$ has no nontrivial primitive elements, because $2z = z \implies z = 0$.
For a less trivial example, consider the group algebra $\mathbb{C}[\mathbb{Z}/2\mathbb{Z}]$ with basis $\langle 1, x \rangle$ ($x$ corresponds to the generator of the cyclic group, $x^2 = 1$). Its coalgebra structure is given by $$\begin{align} \Delta(1) & = 1 \otimes 1 & \Delta(x) & = x \otimes x \\ \epsilon(1) &= 1 & \epsilon(x) &= 1 \end{align}$$
Suppose $u = a + bx \in H$ is primitive, where $a,b \in \mathbb C$. Then $\Delta(u) = a (1 \otimes 1) + b (x \otimes x)$ should equal $1 \otimes (a+bx) + (a+bx) \otimes 1$, which is impossible unless $a=b=0$. More generally, I'm almost sure that the group algebra of a finite group has no primitive elements, but I haven't checked all the details yet.
However you can still say something in restricted cases. The Milnor–Moore theorem tells you that a locally conilpotent* cocommutative Hopf algebra $H$ is isomorphic to $\mathbb{U}(\mathbb{P}H)$, that is the enveloping algebra of the Lie algebra of primitive elements. So if $\mathbb{P} H = 0$, then $H = 0$.
*: Let $\pi : H \to H$ be the projector onto the augmentation ideal $\overline{H}$ of $H$. A Hopf algebra $H$ is said to be locally conilpotent if it can be written as a direct colimit $H = \operatorname{colim} K^m$ such that:
This is in particular the case when $H$ is a connected Hopf algebra. This is not the case for a group algebra $\mathbb{C}[G]$ with nontrivial $G$: no matter how many times you iterate the coproduct on $g \in G$, none of the factors will ever fall into the augmentation ideal.
For more details about this notion of locally conilpotent and a proof of the Milnor–Moore theorem, I refer you to Benoit Fresse, Homotopy of Operads and Grothendieck-Teichmüller Groups, chapter I.7.