Are there mathematically interesting symmetric matrices with the other symmetries of the square?

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Symmetric matrices are square arrays of integers with a symmetry with respect to the main diagonal. However, there are several other symmetries of the square (symmetry with respect to the other diagonal, rotation by 90°, rotation by 180°, symmetry with respect to a horizontal or vertical axis).

Are some of the matrices invariant under the other symmetries of the square mathematically interesting?