Well, if it is undiscovered, then actually we cannot know whether it exists or not.
But i am wondering if theorems/equalities like $Pythagorean$ $Theorem$ or maybe $Fermat's$ $Last$ $Theorem$ have been discovered in the recent past.
So, can we know (or feel) that a very basic theorem exists, but hasn't been discovered yet?
This question came to my mind when I learned that as people thought that the boundary/end of geometry has almost been reached, Riemann founded the Riemann Geometry.
Examples are the Euler line and Morley's miracle. Both are theorems that in principle could have been proved by the Greeks, but took more than a thousand years to notice. It is certainly possible that many such are lurking in the woodwork.