Consider the integral: $$ I(a)=\int_a^\infty e^x E_1(x)\dfrac{dx}{x}, $$ where $a>0$ and $E_1(x)$ is the exponential integral function.
I would like to better understand the behavior of $I(a)$ for $a\to 0+$. For example, from the double inequality $$ \dfrac{1}{x+1}<e^{x}E_1(x)<\dfrac{1}{x},\ \ x>0, $$ we readily get $$ \log(1+1/a)<I(a)<\dfrac{1}{a}. $$
The (more fine) double inequality $$ \dfrac{1}{2}\log(1+2/x)<e^{x}E_1(x)<\log(1+1/x),\ \ x>0, $$ yields $$ 1/12 (\pi^2 + 3 \log^2(2) + 3 \log(a/4)\log(a) + 6 Li_2(-a/2))<I(a)<-Li_2(-1/a), $$ where $Li_2(x)$ is the poly-log function.
Can these bounds be refined? For example, are there tight bounds for the poly-log function?
$$I(a)=\int_a^\infty e^x E_1(x)\dfrac{dx}{x}=\int_a^\infty \frac{e^x}xdx\left(\int_x^\infty\frac{e^{-t}}tdt\right)\overset{t=xs}{=}\int_a^\infty \frac{e^x}xdx\left(\int_1^\infty\frac{e^{-xs}}sds\right)$$ $$\overset{x=at}{=}\int_1^\infty \frac{e^{at}}tdt\left(\int_1^\infty\frac{e^{-ats}}sds\right)=\int_1^\infty\frac{dt}t\int_0^\infty\frac{e^{-ats}}{1+s}ds$$ Integrating by part $$=\int_1^\infty\frac{dt}t\left(\ln(1+s)e^{-ats}\,\bigg|_0^\infty+at\int_0^\infty\ln(1+s)e^{-ats}ds\right)=\int_0^\infty\frac{\ln(1+s)}se^{-as}ds\tag{1}$$ Making the substitution $as=t$ and integrating by part $$=\ln s\ln\frac{s+a}ae^{-s}\,\bigg|_0^\infty-\int_0^\infty\frac{\ln s}{a+s}e^{-s}ds+\int_0^\infty\ln s\ln\frac{a+s}ae^{-s}ds$$ $$=\int_0^\infty\ln s\ln(a+s)e^{-s}ds+\gamma\ln a-\int_0^\infty\frac{\ln s}{a+s}e^{-s}ds$$ The first integral converges at $a=0$; therefore $$I(a)=\gamma\ln a+\int_0^\infty\ln^2s\,e^{-s}ds-\int_0^\infty\frac{\ln s}{a+s}e^{-s}ds+o(1)\tag{2}$$ Using $\displaystyle \frac1{s+a}=\int_0^\infty e^{-t(s+a)}dt$, the last integral in (2) can be evaluated. Changing the order of integration, $$-\int_0^\infty\frac{\ln s}{a+s}e^{-s}ds=-\int_0^\infty e^{-ta}dt\int_0^\infty\ln s\,e^{-s(t+1)}ds$$ $$=-\int_0^\infty\frac{dt}{1+t}e^{-at}\left(-\gamma-\ln(1+t)\right)=e^a\int_1^\infty\frac{\ln x}xe^{-ax}dx+\gamma e^a\int_1^\infty\frac{e^{-ax}}xdx$$ Integrating by part and keeping only non-vanishing at $a\to 0$ terms, we get $$-\int_0^\infty\frac{\ln s}{a+s}e^{-s}ds=\frac{e^a}2\int_a^\infty(\ln x-\ln a)^2e^{-x}dx-\gamma\ln a+\gamma e^a\int_a^\infty\ln xe^{-x}dx$$ $$=\frac{\ln^2a}2+\frac12\int_0^\infty\ln^2xe^{-x}dx-\gamma^2+o(1)=\frac{\ln^2a}2+\frac{\pi^2}{12}-\frac{\gamma^2}2+o(1)\tag{3}$$ Putting (3) into (2) $$\boxed{\,\,I(a)=\frac{\ln^2a}2+\gamma\ln a+\frac{\gamma^2}2+\frac{\pi^2}4+o(1)\,\,}$$