Suppose that $\{r_n\}_{n=0}^\infty$ is an enumeration of $\mathbb{Q}^N$ and $U = \bigcup_{n=0}^\infty B(r_n,2^{-n})$. We can use a trivial measure theory argument to prove that $U \neq \mathbb{R}^N$.
I was poking around in Real Analysis by Carothers in the section on Baire category (before measure theory has been developed in the book), and I noticed that there's a problem there that asks to prove that $U \neq \mathbb{R}^N$. There are no hints, but given the placement in the book, the goal is presumably to use Baire category.
I have never seen a non-measure based proof of this result, so I gave it a try. I'm a bit stuck, though. It's clear that Baire tells us that one of the sets $\bigcup_{n=k}^\infty B(r_n,2^{-n})$ for $k \in \mathbb{N}$ must not be dense, but I'm not sure how to use this information to prove the result. Any thoughts would be greatly appreciated.
EDIT: Here are the details on my above claim. Set $U_k = \bigcup_{n=k}^\infty B(r_n,2^{-n})$, which is clearly open. Suppose, BWOC, that each $U_k$ is dense in $\mathbb{R}^N$. Then Baire says that $\bigcap_{k=0}^\infty U_k$ is dense in $\mathbb{R}^N$, but on the other hand by construction $\bigcap_{k=0}^\infty U_k = \varnothing$. This contradiction means we must have $E_k$ not dense for some $k$.
EDIT 2: As pointed out in the comments below, this argument doesn't seem to fly. So, back to square one...
You can get inspiration from measure theory without actually using it, as follows.
Let $D$ be any straight line in ${\mathbb R}^N$ (which we will identify with $\mathbb R$). For any $n\geq 0$, $I_n=B(r_n,2^{-n}) \cap D$ is a (possibly empty) open line segment of length at most $2\times 2^{-n}$. So the sum of the lengths of the $I_n$ is at most $4$. It is then easy to construct by induction a decreasing sequence of compact subsets $(K_n)_{n\geq 1}$ of $D$, such that for each $n$, $K_n$ is disjoint from $I_n$, and $K_n$ is a finite union of closed line segments whose lengths sum up to at least $2015-\sum_{k=1}^{n}{\textsf{length}}(I_k)$.
By the Heine-Borel property, $\bigcap_{n\geq 1}K_n$ is nonempty and any $x$ in it will be outside your $U$.