Basic trigonometry - $\sin{(-a)} = -\sin{(a)}$

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If $\sin (-a) = -\sin (a)$, why isn't $\sin (-210°) = - \sin (180° + 30°) = - \sin (30°) = -0.5$ ?

The answer is positive $0.5$ instead.

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\begin{align} \sin (-210°) &= -\sin(210°) \tag{$\sin(a) = -\sin(a)$} \\ &= - \sin (180° + 30°) \\ &= - (-\sin (30°)) \tag{$\sin(180° + a) = -\sin(a)$} \\ &= 0.5 \end{align}

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When you have such doubts, always think to the geometrical meaning of $\sin \theta$ and in which quadrant $\theta$ is.

Notably $\sin \theta$ represent the $y$-coordinate of the point on the trigonometric circle, since $\theta=-210°=-210°+360°=150°$ is in the second quadrant, $\sin -210°$ must be positive.

Of course, to determine the value you need more precise evaluation by trigonometric identities but you need to have the correct idea and feeling on the sign.

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For a very simple and important reason, surprisingly not enough emphatized in the previous two answers, in my opinion. \begin{align} \sin(-210°)&=-\sin(210°)=\\ &=-\sin(180°+30°)\color{red}{\ne}\\ &\color{red}{\ne}-(\sin(180°)+\sin(30°)). \end{align} The first equality holds because, as you know, $$\sin(-a)=-\sin(a)$$ for all $a\in\mathbb R$. But while $f(-a)=-f(a)$ is a property of linear functions, is important to say that

$\sin(a)$ is not a linear function of $a$

and, for example, $$\sin(a+b)=\sin(a)+\sin(b)$$ does not hold for all $a,b\in\mathbb R$. In particular, it holds for $a=180°$ and $b=0°$ but it does not hold for $a=180°$ and $b=30°$. On the other hand we know that $$\sin(180°+b)=-\sin(b)$$ holds for all $b\in\mathbb R$.

Hence: \begin{align} \sin(-210°)&=-\sin(210°)=\\ &=-\sin(180°+30°)=\\ &=-(-\sin(30°))=\\ &=\sin(30°)=\frac{1}{2}>0. \end{align}