How to prove that only four dimensional division algebra (noncommutative) over $\Bbb{Q}$ is rational quaternions?
After a bit of internet research, I am very sure about the above statement, if not please surprise me!
How to proceed at such statement? Just letting $D$ be a $4$ dimensional division algebra, is not taking me forward.
It's not true. It would be true if $\mathbb Q$ were replaced by $\mathbb R$ in your statement, and the rational quaternions replaced with the real quaternions. There is an infinite family of pairwise non-isomorphic quaternion algebras over $\mathbb Q$ which are simple central divison algebras of dimension $4$ over $\mathbb Q$, and of which the rational quaternions are one example.
Moreover any field extension of $\mathbb Q$ of degree $4$ is a commutative division algebra over $\mathbb Q$ and there are infinitely many of those as well.