In mathematics and computabiltiy theory, we treat all inputs and intermediate results and final outputs as natural number. While algorithms/programs themselves are considered natural numbers, here we treat these programs/functions/algorithms as just computable functions.
The question is, when the function operates on an input to produce an output, can we consider the operation of function as using only a number of arithmetic operations (addition, subtraction, multiplication and division) on an input? Or does the use of if/else make the aforementioned not true?
If this is true, is the number of arithmetic operations polynomially proportional to the lowest time complexity bound possible for solving a problem? (That is, if the lowest time complexity is $\text{O(whatever)}$, then the number of arithmetic operations is $\text{O(whatever}^k)$ where $k$ is some rational number.)
This is a short and quick answer, an expert probably will give you more details in brief. The answer is No, and you are right, the if/else statements are necessary to make the language Turing complete. But remember that Peano arithmetic, a first order logic (which includes equivalents to if\else) axiomatization of arithmetic, is closely related to computability and Turing machines. Wikipedia gives a great summary of all this.