Let $M$ be a smooth $n$ dimensional manifold, and let $1 \le k < n$. Let $\omega \in \Omega^k(M)$ be a closed $k$-form on $M$.
Let $p \in M$. Do there exist coordinates around $p$, such that $\omega=a_{i_1i_2\dots i_k}dx^{i_1} \wedge dx^{i_2} \dots \wedge dx^{i_k}$, where $a_{i_1i_2\dots i_k}$ are constants?
That is, I ask whether every closed differential form be locally expressed via constant coefficients.
Edit:
I forgot to require that $\omega$ should be everywhere non-zero. Otherwise, as mentioned by Paulo Mourão, one can take $xdx$ on $M=\mathbb{R}$.
Let me generalize somewhat Jack Lee's answer. Assume $V,W$ are finite dimensional real vector spaces and let $\mu \in \Lambda^k(V)^{*}, \nu \in \Lambda^k(W)^{*}$ be two $k$-alternating forms on $V$ and $W$ respectably. Let's say that $\mu$ and $\nu$ are equivalent if there exists an isomorphism $T \colon V \rightarrow W$ such that for all $v_1, \dots, v_k \in V$ we have $$ \nu(Tv_1, \dots, Tv_k) = \mu(v_1, \dots, v_k). $$ In order words, $\nu$ and $\mu$ are equivalent if $T^{*}(\nu) = \mu$. By functoriality of the pullback, this is an equivalence relation.
Claim: Let $\omega$ be a $k$-form on a manifold $M^n$ and let $p \in M$. A necessary condition for the existence of a coordinate system around $p$ in which $\omega$ has constant coefficients is that there exists a neighrhood $U$ of $p$ in which $\omega_{p'}$ is equivalent to $\omega_p$ for all $p' \in U$.
Proof: If $\varphi \colon V \rightarrow U \subseteq M$ is a coordinate system in which $\omega$ has constant coefficients, then $\varphi^{*}(\omega|_{V}) = \sum_{I} a_I dx^{I}$. Set $\omega_0 = \sum_{I} a_I dx^{I} \in \Lambda^k(\mathbb{R}^n)^{*}$ and let $p' = \varphi(q') \in U$. Then $d\varphi|_{q'} \colon \mathbb{R}^n \rightarrow T_{p'}M$ is a linear isomorphism which gives an equivalence between $\omega_{p'}$ and $\omega_0$. Since $p' \in U$ was arbitrary, $\omega_{p}$ is also equivalent to $\omega_0$ and so $\omega_p$ and $\omega_{p'}$ are equivalent.
When $k \in \{1, 2, n-2, n-1, n\}$, one can classify explicitly when two $k$-forms are equivalent using the rank. For the other cases and general $n$, it seems to be an open problem (you asked about it before here) but having constant rank is definitely not sufficient. For some examples showing that constant rank or local equivalence is not sufficient, see here.