If I have a vector $(0,4,4)$ and was finding perpendicular unit vectors to this, is it the same case as finding perpendicular unit vectors for the vector $(4,4)$? Meaning a maximum of two possible perpendicular unit vectors?
When I draw and visualize the space that $\Bbb R^3$ vectors occupy, it would seem logical to me that if one component is equal to zero then the vector could be treated as if it was in $\Bbb R^2$ for its non-zero components.
Any nonzero vector in $\mathbb{R}^3$ will have an orthonormal set spanned by two vectors.
If you ignore the zero component and draw it in $\mathbb{R}^2$, the two basis vectors for the orthonormal set will be one on the paper (orthogonal in the $\mathbb{R}^2$plane) and another vector "coming out of the paper," orthonormal to the first.