Can I use $\{\lambda_i,\mu_i\}$ to describe a matrix's eigenvalues and account for their multiplicity?
Here $\lambda_i$ would be the eigenvalues, and $\mu_i$ would be its multiplicity.
(I need the multiplicity of the eigenvalues in my work, in set notation, but don't want to use the notation such as $\{1,1,1,2,3,3,4,4,4,4\}$.)
It's not appropriate since sets are inherently unordered. You could use an ordered pair $(\lambda_i,\mu_i)$. Since you have a list of eigenvalues with their multiplicity, a set of ordered pairs
$$\left\{(\lambda_1,\mu_1),(\lambda_2,\mu_2), \dotsc, (\lambda_n,\mu_n)\right\} $$
would probably be best.