Let $f\in \mathcal S'(\mathbb R)$ be a Schwartz distribution. Given $\rho \in C^\infty_c(\mathbb R)$ define the convolution as the function $$x\mapsto (f\ast\rho)(x):=\langle f, \rho (\cdot -x)\rangle.$$
I believe this function should be smooth. Anyway my question is: suppose further that $\rho\geq 0$ and $\int \rho = 1$ and for $\varepsilon>0$, define $$\rho_\varepsilon(x):=\frac{1}{\varepsilon}\rho(x\varepsilon^{-1}).$$ Then is it the case that $f\ast\rho_\varepsilon\to f$ in $\mathcal S'(\mathbb R)$ as $\varepsilon\to 0$?
To answer your question, yes. For a proof, first require a few prerequisites. From F. G. Friedlander and M. Joshi's Introduction to the Theory of Distributions, we have
We borrow the notation $$ f_\varepsilon = f * \rho_\varepsilon $$ for your tempered distribution $f$. We also define $\mathcal D(\mathbb R) = C_c^\infty(\mathbb R)$ to be a set of "test functions" with dual space "the distributions" $\mathcal D'(\mathbb R)$. The relation to the Schwartz functions $\mathcal S(\mathbb R)$ and the tempered distributions $\mathcal S'(\mathbb R)$ is $$ \mathcal D \subset \mathcal S \subset \mathcal S' \subset \mathcal D'; $$ it's true that
from which it follows that all inclusions are dense.
We make two key observations from the above two theorems before finally attacking the proof.
Finally, $f_\varepsilon \to f$ in $\mathcal{S}'(\mathbb R)$ as $\varepsilon \to 0$ iff for all $\varphi \in \mathcal S(\mathbb R)$, we have $\langle f_\varepsilon, \varphi \rangle \to \langle f, \varphi \rangle$ as $\varepsilon \to 0$. To prove this is the case, let $\varepsilon' > 0$. Then
\begin{align*} f - f_\varepsilon &= f - \psi_n + \psi_n - f_\varepsilon \\ &= (f - \psi_n) + (\psi_n - \psi_n * \rho_\varepsilon) + (\psi_n * \rho_\varepsilon - f_\varepsilon) \\ \implies \left| \left\langle f - f_\varepsilon, \varphi \right\rangle \right| & \leq \left| \left\langle f - \psi_n, \varphi \right\rangle \right| + \left| \left\langle \psi_n - \psi_n * \rho_\varepsilon, \varphi \right\rangle \right| + \left| \left\langle \psi_n * \rho_\varepsilon - f_\varepsilon, \varphi \right\rangle \right| \end{align*} Regardless of $\varepsilon$, we may bound the first and third terms of the latter expression by $\varepsilon'$ if we choose $n$ sufficiently large according to $(1)$ and $(2)$. This gives us $$ \left| \left\langle f - f_\varepsilon, \varphi \right\rangle \right| \leq 2 \varepsilon' + \left| \left\langle \psi_n - \psi_n * \rho_\varepsilon, \varphi \right\rangle \right|, $$ and then applying $(3)$, we have $$ \left| \left\langle f - f_\varepsilon, \varphi \right\rangle \right| \leq 3 \varepsilon' $$ for sufficiently small $\varepsilon$, which proves the claim.