Catalan numbers are $c_n=\frac{1}{n+1}{\binom {2n}{n}}$.
Prove that $\sum_{k=1}^n c_k\equiv 1 \mod 3 \iff$ The digit $2$ appears in the ternary representation of $n+1$.
I was shown the solution a while ago and forgot it: It relies on finding some short identity that $c_n$ satisfy when considered modulo $3$, and using Lucas' theorem: $\binom{n}{k}$ is divisible by 3 iff when adding $k+(n-k)$ in base $3$ there is a carry.
$$\binom{2k+2}{k+1} -\binom{2k}{k}-\frac 1{k+1}\binom{2k}{k} = \binom{2k}{k} \left(\frac{(2k+2)(2k+1)}{(k+1)(k+1)}-1-\frac1{k+1}\right) = \binom{2k}{k} \frac{3k}{k+1} = 3 \binom{2k}{k+1}. $$
Which is clearly a multiple of three.