For $x \in [0,\pi/2]$, $\sin(x)$ ranges over $[0,1]$. So every rational number in $[0,1]$ is the sine of some $x \in [0,\pi/2]$.
Q. Is there any characterization of the $x$ for which $\sin(x)$ is rational?
I am not quite sure what shape such a characterization might take. Something like: If $x$ satisfies such-and-such conditions, then $\sin(x)$ is rational. Perhaps there is at least a partial characterization?
The only nice $x$ in this range for which $\sin x$ is rational are $0$, $\pi/6$, and $\pi/2$. Every other preimage of a rational number is neither rational nor a rational multiple of $\pi$.
(In fact I'm almost sure that if $\sin x$ is rational and not in $\{-1,-\frac12,0,\frac12,1\}$, then $x$ is algebraically independent of $\pi$).