How to check whether the two quadratic forms \begin{equation} x_1^2 + x_2^2 \quad \text{(I)}\end{equation} and \begin{equation} 2x_1x_2 \quad \text{(II)} \end{equation}
are equivalent on each of the spaces $\mathbb{F}_3^2\, \text{and}\,\mathbb{F}_5^2$? I know that these forms correspond to the two matrices \begin{pmatrix} 0 & 1 \\ 1 & 0 \end{pmatrix} in case (I) and \begin{pmatrix} 1 & 0 \\ 0 & 1 \end{pmatrix} in case (II). But what do I do with those and what difference do the different fields make?
The characteristic of the field makes a big difference in the computations. I would start by comparing the discriminates of the two matrices.
Over both fields, the discriminants are $\pm 1$. The question is: do $\pm1$ differ by a square factor in both fields or not?
Over the field of five elements, $1\cdot 3^2\equiv -1\pmod 5$, but over the field of three elements, $a^2\equiv 1\not\equiv -1\pmod 3$ for all nonzero $a$.
After some work, you can find that the two matrices are cogredient this way: $$\begin{bmatrix}3&1\\1&3\end{bmatrix}\begin{bmatrix}1&0\\0&1\end{bmatrix}\begin{bmatrix}3&1\\1&3\end{bmatrix}=\begin{bmatrix}0&1\\1&0\end{bmatrix}$$
Here's an elementary brute force way to figure this out using just algebra. From $$ \begin{bmatrix}a&b\\c&d\end{bmatrix}\begin{bmatrix}1&0\\0&1\end{bmatrix}\begin{bmatrix}a&c\\b&d\end{bmatrix}=\begin{bmatrix}a&b\\c&d\end{bmatrix}\begin{bmatrix}a&c\\b&d\end{bmatrix}=\begin{bmatrix}a^2+b^2&ac+bd\\ac+bd&c^2+d^2\end{bmatrix}=\begin{bmatrix}0&1\\1&0\end{bmatrix} $$
we have already learned that $a^2=-b^2$, $c^2=-d^2$ and $ac+bd=1$. Earlier I noted that $1$ differs from $-1$ by a factor of $3^2$, so I suppose my change of basis matrix has determinant $3$, so $ad-bc=3$.
Now
$$ a= a^2c+adb\\ =-b^2c+adb\\ = b(ad-bc)\\ = 3b $$
Similarly $$ c= ac^2+dcb\\ =-d^2a+dcb\\ = -d(ad-bc)\\ = -3d = 2d $$
We've consumed the two equations involving squares, and now we combine the other two.
We have that
$$ 1=ac+bd=6bd+bd=7bd=2bd $$
Hence, $bd=3$ or in other words $d=3/b$. At this point we have $a,c,d$ all in terms of $b$ ($a=3b$, $d=3/b$, $c=2d=1/b$).
Choosing $b=1$, we arrive at $a=d=3$, $b=c=1$.