This is related to a previous post of mine: How do I prove that the typical fibre of the associated bundle $(P_F:=(P\times F)/\sim_G,\pi_F,M)$ is $F$? so I apologise (and please let me know) if I'm breaking any rules of the site.
To tackle this problem, I've tried a different route by first defining a map $$\begin{alignat*}{2} j:A_x&\longrightarrow F \\ [(p,f)]&\longmapsto j([(p,f)]):=f \end{alignat*}$$
where $x\in M$ and $A_x:=\{[(p,f)]\in P_F \mid \pi_F([(p,f)])=x\}$, with $\pi_F$ the projection for the associated bundle. The equivalence relation is defined $[(p',f')]\sim_G [(p,f)] :\iff \exists g\in G: p'=p\triangleleft g:f'=g^{-1}\triangleright f$.
I want to show that this is well-defined (and ultimately a bijection, but I haven't got there yet), i.e $j([(p',f')])=j([(p,f)])$. My attempt so far is this: $$j([(p',f')]) = j([(p\triangleleft g,g^{-1}\triangleright f)]) = g^{-1}\triangleright f=j([(p,g^{-1}\triangleright f)])$$ but I'm not sure where to go next. I'm not entirely confident that the map is indeed well defined and that I'm not trying to prove something true that is simply false, any help would be much appreciated.
Let me change your notation slightly so I can wrap my head around it. Let $P \xrightarrow{\pi} M$ be a principal $G$ bundle and $F$ a left $G$ space. If $p \in P$ denote the right action of $G$ on $P$ by $p \cdot g$ and if $f \in F$ the left action of $G$ on $F$ by $g \cdot f$. Then $P_F = (P \times_G F)$ where we have $[p,f] = [p \cdot g, g^{-1} \cdot f]$. If $m \in M$, we wish to identify the fiber $(P_F)_m$ with $F$ by a homeomorphism.
First consider the product $P \times F$ and fix a basepoint $b \in P$ such that $\pi(b) = m$, then consider $F_b = \lbrace b \rbrace \times F$. Then for any point $p$ in $P$ such that $\pi(p) = m$, there exists a unique $g \in G$ such that $p = b \cdot g$. So if $(p,f) \in P \times F$ and $p = b \cdot g$, then define a map $(P \times_G F)_m \to F_b$ by $[p,f] \mapsto (b,gf)$. This is well defined because $[p,f] = [bg,f] = [b,gf]$ and $[ph,h^{-1}f] = [bgh,h^{-1}f] = [b,ghh^{-1}f] = [b,gf] \mapsto (b,gf)$.
I claim this map is a homeomorphism by providing an inverse $F_b \to (P \times_G F)_m$ given by $(b,f) \mapsto [b,f]$. Then $(b,f) \mapsto [b,f] \mapsto (b,f)$ is the identity and $[p,f] = [bg,f] \mapsto (b,gf) \mapsto [b,gf] = [p,f]$ is also the identity.
Now it is clear that $F_b = \lbrace b \rbrace \times F$ is homeomorphic to $F$.