Suppose that $\Gamma^{\beta}_{i\alpha}$ are Christoffel symbols for a connection with respct to a (local) basis $\{E_1,...,E_n\}$. I tried to prove that the Christoffel symbols for a dual connection with respect to the dual basis $\{\theta_1,...,\theta_n\}$ are then $-\Gamma_{i\alpha}^{\beta}$. I checked that the two expressions: one which defines the dual connection, and the expression $-\Gamma_{i\alpha}^{\beta}dx^i \otimes \theta_{\alpha}$ coincide but only for evaluated on pairs $(\partial_i,E_{\alpha})$. My question is: Is it enough in order to claim that the Christoffel's symbols of the dual connection are $-\Gamma$'s?
Christoffel's symbols for a dual connection
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It's been quite awhile since I've looked at a differential geometry book which covers this stuff, so this might not be exactly what is wanted here, but as I recall the connection's action on the dual basis $\theta_\mu$ may be found from its action in terms of the basis $E_\nu$, i.e., from the formula
$\nabla_\gamma E_\nu = \sum_\kappa \Gamma_{\nu \gamma}^\kappa E_\kappa \tag{1}$
as follows: the dual basis $\theta_\mu$ to $E_\nu$ satisfies
$\theta_\mu(E_\nu) = \delta_{\mu \nu} \tag{2}$
for all pairs of indices $\mu, \nu$. Applying $\nabla_\gamma = \nabla_{E_\gamma}$ to this equation yields
$\nabla_\gamma(\theta_\mu(E_\nu)) = 0, \tag{3}$
and since we want the Leibniz rule for derivatives of products to apply to $\theta_\mu(E_\nu)$ we must have
$\nabla_\gamma(\theta_\mu(E_\nu)) = (\nabla_\gamma \theta_\mu)(E_\nu) +\theta_\mu(\nabla_\gamma E_\nu); \tag{4}$
when (4) is combined with (3) we obtain
$(\nabla_\gamma \theta_\mu)(E_\nu) + \theta_\mu(\nabla_\gamma E_\nu) = 0, \tag{5}$
or
$(\nabla_\gamma \theta_\mu)(E_\nu) = -\theta_\mu(\nabla_\gamma E_\nu); \tag{6}$
using the formula (1) in (6) we see that
$(\nabla_\gamma \theta_\mu)(E_\nu) = -\theta_\mu(\sum_\kappa \Gamma_{\nu \gamma}^\kappa E_\kappa) = -\Gamma_{\nu \gamma}^\mu. \tag{7}$
(7) expresses the components of $\nabla_\gamma \theta_\mu$ via evaluation on the vector basis $E_\nu$; from this it follows from a standard but basic linear algebraic argument that
$\nabla_\gamma \theta_\mu = -\sum_\sigma \Gamma_{\sigma \gamma}^\mu \theta_\sigma. \tag{8}$
(8) is the formula for the covariant derivative of $\theta_\mu$; we see that the Christoffel symbols $\Gamma_{\rho \tau}^\sigma$ occuring in the expressions for $\nabla_\gamma E_\mu$ and $\nabla_\gamma \theta_\mu$ are indeed the negatives of one another, and summed over different indices as well, a lower for dual vectors and an upper index for members of the original basis vectors themselves. From this point of view, the Christoffel symbols for the dual basis $\theta_\mu$ are indeed the $-\Gamma$, where the $\Gamma$ are the Christoffel symbols for the basis $E_\mu$.
That's how I'd address it, in any event.
It should be observed that in the above discussion, the dual connection is in fact defined by (4); we stipulate the $\nabla_\gamma$ must so act on $\theta_\mu(E_\nu)$. With such stipulation and definition, the connection coefficients for the dual basis are as shown. The mixed notation $-\Gamma_{i\alpha}^{\beta}dx^i \otimes \theta_{\alpha}$ is one I have occasionally seen but with which I am not overly familiar, and since our OP truebaran doesn't specify how the corresponding mixed dual connection is defined, I will leave further discussion of this particular point without further comment.
Hope this helps. Cheers,
and as always,
Fiat Lux!!!
You seem to have switched notation in your question as there appears $\partial_i$ and $dx^i$, but you didn't start with a coordinate frame. If I understand your question correctly, then the answer is yes. What you are trying to find is $C_{ij}^k$ given by the formula $$\nabla_{E_i}\theta_j=C_{ij}^k\theta_k$$To find these functions evaluate both sides of this equation at $E_l$.
We have that $C_{ij}^k(\theta_k)E_l=C_{ij}^k=C_{ij}^l$, while by definition $$(\nabla_{E_i}\theta_j)(E_l)=E_i(\theta_j(E_l))-\theta_j(\nabla_{E_i}E_l)=-\theta_j(\nabla_{E_i}E_l)=-\theta_j(\Gamma_{il}^pE_p)=-\Gamma_{il}^j$$