Clarifying divergence Theorem knowledge

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I understand the Divergence theorem is as follows,

$\iiint\limits_{v} (\nabla \bullet \textbf{F}) \;dV= \iint\limits_{dv} \textbf{F} \bullet d \textbf{S}$

My query is if i already know $(\nabla \bullet \textbf{F})= 0$ then can i assume the following,

$(\nabla \bullet \textbf{F})\iiint\limits_{v} \;dV= \iint\limits_{dv} \textbf{F} \bullet d \textbf{S}= 0$.

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The Divergence Theorem states that given $V\subseteq\mathbb{R^n}$ which has a smooth boundary $S$, and given a differentiable vector field $\mathbf{F}$ (of class $C^1$) which is continuous in a neighborhood of $V$, then the following is true:

$$\iiint_V\left(\nabla\cdot\mathbf{F}\right)\,dV=\iint_S \left(\mathbf{F}\cdot\mathbf{n}\right) \,dS$$

with $\mathbf{n}$ being the normal vector of $\mathbf{F}$ (I'll let you see the difference with that you wrote).

In your case, having $\nabla\cdot\mathbf{F}=0$ (which means that there is no net flux), gives: $$\iiint_V\left(\nabla\cdot\mathbf{F}\right)\,dV=\iiint_V0\cdot\,dV=0\implies\iint_S \left(\mathbf{F}\cdot\mathbf{n}\right) \,dS=0$$ Please note that: $$\iiint_V\left(\nabla\cdot\mathbf{F}\right)\,dV\neq\left(\nabla\cdot\mathbf{F}\right)\iiint_V\,dV.$$

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No.

Let's look at your equation:

$$ \nabla \cdot \mathbf F \iiint_vdV=\iint_{dv}\mathbf F\cdot dS $$

Putting the meaning of the divergence theorem aside, let's just see the values of the LHS and RHS in your equation. The LHS is a function because $\nabla\cdot \mathbf F$ is a function of $(x,y,z)$. However, the RHS is a number. Obviously, the two quantities cannot be equal.