It is well known that $$\operatorname{R}(-e^{-\pi})=-\cfrac{e^{-\frac{\pi}{5}}}{1-\cfrac{e^{-\pi}}{1+\cfrac{e^{-2\pi}}{1-\cfrac{e^{-3\pi}}{1+\ddots}}}}=\frac{\sqrt{5}-1}{2}-\sqrt{\frac{5-\sqrt{5}}{2}}$$ where $\operatorname{R}$ is the Rogers-Ramanujan continued fraction: $$\operatorname{R}(q)=\cfrac{q^{\frac{1}{5}}}{1+\cfrac{q}{1+\cfrac{q^2}{1+\cfrac{q^3}{1+\ddots}}}},\, q=e^{\pi i\tau}.$$
But I'm interested in $\operatorname{R}(e^{-\pi})$. Numerically, I checked that it agrees with the root of the following octic equation near $x=\frac{1}{2}$ to at least $16$ decimal places: $$x^8+14x^7+22x^6+22x^5+30x^4-22 x^3+22 x^2-14x+1=0;$$ the root turns out to be equal to $$\frac{\sqrt{5}-1}{2}\frac{\sqrt[4]{5}+\sqrt{2+\sqrt{5}}}{\sqrt{5}+\sqrt{2+\sqrt{5}}}.$$
So is it true that $$\frac{e^{-\frac{\pi}{5}}}{1+\cfrac{e^{-\pi}}{1+\cfrac{e^{-2\pi}}{1+\cfrac{e^{-3\pi}}{1+\ddots}}}}=\frac{\sqrt{5}-1}{2}\frac{\sqrt[4]{5}+\sqrt{2+\sqrt{5}}}{\sqrt{5}+\sqrt{2+\sqrt{5}}}?$$ The $2$'s and $5$'s under the square roots seem very suggestive of the nature of $\operatorname{R}$.
Also, how could it be proved in that case?
Using $$\frac{1}{\operatorname{R}(q)}-\operatorname{R}(q)=\frac{\left(q^{\frac{1}{5}};q^{\frac{1}{5}}\right)_{\infty}}{q^{\frac{1}{5}}(q^5;q^5)_{\infty}}+1$$ and $$\frac{\eta (e^{-\pi\sqrt{n}})}{\eta \left(e^{-\frac{\pi}{\sqrt{n}}}\right)}=n^{-\frac{1}{4}},\, n\gt 0$$ (where $\eta (q)=q^{\frac{1}{12}}\prod_{n\ge 1}(1-q^{2n})$ is the Dedekind eta function), I've been able to evaluate $\operatorname{R}(-e^{-\pi})$ and $\operatorname{R}(e^{-2\pi})$, but I don't know how could it be used to evaluate $\operatorname{R}(e^{-\pi})$. Perhaps something else is necessary.
I was inspired by Ramanujan's first letter to Hardy, where Ramanujan's $7\text{th}$ theorem states that $$\cfrac{1}{1+\cfrac{e^{-\pi\sqrt{n}}}{1+\cfrac{e^{-2\pi\sqrt{n}}}{1+\cfrac{e^{-3\pi\sqrt{n}}}{1+\ddots}}}}$$ can be exactly found for any $n\in\mathbb{Q}^{+}$.
$R(q)$ is expressible in terms of radicals for every $q=e^{2\pi i \tau}$, where $\tau$ is an imaginary quadratic irrational in the upper half plane. OP already observed it for $R(e^{-\pi\sqrt{n}})$. It is easy to obtain an algebraic equation satisfied by $R(q)$, but unwinding into radical form is more difficult.
The Roger-Ramanujan continued fraction has many equivalent forms:$$R(q) = \cfrac{q^{1/5}}{1+\cfrac{q}{1+\cfrac{q^2}{1+\cfrac{q^3}{1+\ddots}}}} = q^{1/5} \prod_{n=1}^\infty \frac{(1-q^{5n-1})(1-q^{5n-4})}{(1-q^{5n-2})(1-q^{5n-3})}.$$
Writing $q=e^{2\pi i \tau}$. From the latter expression, it can be shown that $R$ is modular of level $5$, therefore $R$ and the $j$-invariant has an algebraic relation of degree $[\bar{\Gamma}(1):\bar{\Gamma}(5)] = 60$ (bar means quotienting out center): $$\tag{*} R^5 (R^{10}+11 R^5-1)^5j+(R^{20}-228 R^{15}+494 R^{10}+228 R^5+1)^3 = 0.$$
You are concerned with $R(e^{-\pi})$. Since $j(i/2) = 287496$, $R$ is a root of degree $60$ equations over $\mathbb{Z}$. $(*)$ factors over $\mathbb{Q}$, the octic $$R^8+14R^7+22R^6+22R^5+30R^4-22 R^3+22 R^2-14R+1$$ appears as one of the factors. Numerical evaluation will tell you that $R(e^{-\pi})$ is indeed a root of this factor, completing the proof.
The other $59$ roots of $(*)$ are values of $R$ at $\Gamma(1)$-orbit of $i/2$ which are $\bar{\Gamma}(5)$-inequivalent.