Definition 1. A topological property $P$ is expansive(contractive) if for any topology $ \tau$ with property $P$ any finer (coarser) topology $ \tau^{*} $ also has property $ P $.
Definition 2. If $P$ is an expansive topological property and $Q$ is a contractive topological property then $P$ and $Q$ are called complementary if a topology is minimal $P$ if and only if it is maximal $Q$.
Definition 3. A topological space is called $KC$ space if every compact subset is closed.
Theorem: X is maximal compact $ \Longleftrightarrow $ X is KC-minimal.
Therefore, $KC$ and compactness are complementary.
1: What property can be placed instead of compactness or $KC$ to complement?
2: Do you give me some examples of topological properties to complement each other?
Let $P$ be an expansive property and let $Q$ be a contractive property. There are different types of complementarity relating the following induced poperties: (1) minimal $P$, (2) maximal $Q$, (3) $P$ and $Q$.
The definition of complementary properties you mention (iirc defined by Larson) demands the equivalence of minimal $P$ and maximal $Q$, i.e. (1) $\iff$ (2). Of course a topology that satifies the equivalent properties is also both $P$ and $Q$, but I do not see a reason for the converse. So there may be complementary properties $P$ and $Q$ such that being simultaneously $P$ and $Q$ does not imply being minimal $P$ (and maximal $Q$).
It seems that often you start with properties $P$ and $Q$ such that being simultaneously $P$ and $Q$ implies both minimal $P$ and maximal $Q$, i.e. (3) $\implies$ (1) and (2). Equivalently, there is no $P$ topology strictly coarser than a $Q$ topology. Let us call such properties opposing. It may additionaly happen that minimal $P$ already implies $Q$ (i.e. (2) $\implies$ (3)) and/or that maximal $Q$ already implies $P$ (i.e. (1) $\implies$ (3)). In the best case, all conditions (1), (2), (3) are equivalent, and in particular the properties $P$ and $Q$ are complementary.
Some examples of opposing properties: