We have $\partial_n ( \sigma) = \sum_{i} (-1)^{i} \sigma [ v_1, \dots, \overset { \wedge} v_i, \dots, v_n]$ and we want to show that the composition $$ \delta_n(X) \overset{\partial_n} \to \delta_{n-1}(X) \overset{\partial_{n-1}} \to \delta_{n-2}(X) $$ is zero.
The book goes on to simply write, $$ \partial_{n-1}\partial_n(\sigma)= \sum_{j < i} (-1)^{i} (-1)^{j} \sigma [ v_0, \dots, \overset{\wedge}v_j, \dots, \overset{\wedge}v_i, \dots v_n ]+ $$ $$ \sum_{i < j} (-1)^{i} (-1)^{j-1} \sigma [ v_0, \dots, \overset{\wedge}v_i, \dots, \overset{\wedge}v_j, \dots v_n ]$$
I am not quite able to produce this summation on my own using the definition of the boundary homomorphism. I would like to see the above result more fleshed out if possible.
For $a,b\in\mathbb Z$, let $[a,b]=\{k\in\mathbb Z:a\leq k\leq b\}$. Let $\sigma:\Delta^n\to X$. We have that $$\partial_n(\sigma)=\sum_{i=0}^n\,(-1)^i\,\sigma\mid [e_0,\ldots,\hat e_i,\ldots,e_n].$$ and hence, $$(\partial_{n-1}\circ\partial_n)(\sigma)=\partial_{n-1}\,\big( \,\partial_n(\sigma)\,\big)=\partial_{n-1}\,\big(\,\sum_{i=0}^n\,(-1)^i\,\sigma\mid [e_0,\ldots,\hat e_i,\ldots,e_n]\,\big).$$ $$=\sum_{i=0}^n\,(-1)^i\,\partial_{n-1}\big(\sigma\mid [e_0,\ldots,\hat e_i,\ldots,e_n]\,\big)$$
For $i\in [1,n-1]$, we have that $$\partial_{n-1}\big(\sigma\mid [e_0,\ldots,\hat e_i,\ldots,e_n]\,\big)=\sum_{j=0}^{i-1}\, (-1)^j\,\sigma \mid [e_0,\ldots,\hat e_j,\ldots,\hat e_i,\ldots,e_n]$$ $$+\sum_{j=i+1}^n\,(-1)^{j-1}\,\sigma\mid [e_0,\ldots,\hat e_i,\ldots,\hat e_j\ldots,e_n].$$ When $i=0$, we only have the second summation and when $i=n$, we only have the first summation.
$$(\partial_{n-1}\circ\partial_n)(\sigma)=\sum_{i=1}^n\,(-1)^i\,\big(~\sum_{j=0}^{i-1}\, (-1)^j\,\sigma \mid [e_0,\ldots,\hat e_j,\ldots,\hat e_i,\ldots,e_n]~\big)$$ $$+\sum_{i=0}^{n-1}\,(-1)^i\,\big(\sum_{j=i+1}^n\, (-1)^{j-1}\,\sigma\mid [e_0,\ldots,\hat e_i,\ldots,\hat e_j\ldots,e_n]~\big).$$ $$=\sum_{i=1}^n~\sum_{j=0}^{i-1}\,(-1)^{i+j}\,\sigma\mid [e_0,\ldots,\hat e_j,\ldots,\hat e_i,\ldots,e_n]$$ $$-\sum_{i=0}^{n-1}~\sum_{j=i+1}^n\,(-1)^{i+j}\,\sigma\mid [e_0,\ldots,\hat e_i,\ldots,\hat e_j,\ldots,e_n].$$ In the second summation, after switching $i$ and $j$ we get $$\sum_{j=0}^{n-1}~\sum_{i=j+1}^n\,(-1)^{i+j}\,\sigma\mid [e_0,\ldots,\hat e_j,\ldots,\hat e_i,\ldots,e_n]$$ $$=\sum_{i=1}^n~\sum_{j=0}^{i-1}\,(-1)^{i+j}\,\sigma\mid [e_0,\ldots,\hat e_j,\ldots,\hat e_i,\ldots,e_n]$$ which is the same as the first summation as both the summations are over the set $\{\,(i,j)\in [1,n]\times [0,n-1]:j<i\,\}$.