Let $S$ be the square $\{x + iy: |x| < 1, |y| < 1\}$ and $f:S \rightarrow S$ a holomorphic function so that $f(0)= 0$ and $f'(0) = 1$. Find $f''(0)$.
It seems like I need to use Cauchy's integral formula but I'm not sure. I guess I'm missing what information I gain by having $f(0)$ and $f'(0)$.
The square is a red herring; it could be any domain whatsoever. The key point is the uniqueness part of the Riemann mapping theorem (as Lukas Geyer hinted):
Considering the appropriate composition of maps and using the above statement, you should be able to show the following:
How does this help finding $f''(a_1)$? In general it doesn't. But in your case, $\Omega_1=\Omega_2$ and $a_1=a_2$, so you have one map with the above properties: the identity map. The uniqueness statement tells you that this is $f$.