In the below proof, how is the second line derived from the first?
The first term in the second line has n replaced by (n+1), I cant see why, specially, because this change is not made in the second term.
I understand the rest of the proof but not this part.
What is the manipulation that is being performed?

It's a reindexing of the sum. The general form is $$ \sum_{n=1}^\infty a_n x^{n-1} = \sum_{n=0}^\infty a_{n+1} x^{n} \tag{1} $$ by a change of variable "$n\leadsto n+1$" (are you comfortable with this?).
To see how it is applied here:
However, in the second sum this is not used. Instead, what is used is simply that $$ \sum_{n=1}^\infty n\binom{\alpha}{n} x^{n} = \sum_{n=1}^\infty n\binom{\alpha}{n} x^{n} + \underbrace{0\cdot \binom{\alpha}{0} x^{0}}_{=0} = \sum_{n=0}^\infty n\binom{\alpha}{n}x^{n}\,, $$ i.e., that adding the term "$a_0 x^0$" to the sum does not change the value here, as $a_0=0$.