Fact: $\arctan (1) + \arctan (2) + \arctan (3) = \pi$.
Conjecture: there is no $n \neq 3$ such that $\arctan (1) + \arctan (2) + \cdots + \arctan (n) = \frac{k\pi}{2}$, with $k$ integer.
I know a stronger result than conjecture is: The product $(1 + 1^2) (1 + 2^2) \cdots (1 + n^2)$ is just a perfect square for $n = 3$