Construct theory with a condition

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I would need some help here. I'm preparing for finals from mathematical logic and as I am browsing through some exercises, I often found these types:

Let's say we have 2 propositions $\phi$ and $\psi$:

a, construct a theory $T$ which is unsatisfiable if $\phi \vDash \psi$

b, using Skolemisation find the theory $T$ which is unsatisfiable if $\phi \vDash \psi$

I would like to get some thoughts about how to approach problems like these. Also, an example with solution would be greatly appreciated.