Consider the set $S=\{ (1),(12),(13),(23),(123),(132)\}$. Let $G$ be a group of permutations of a set $S$. Prove that the orbits of the members of $S$ constitute a partition of $S$.
Now
\begin{eqnarray*} \operatorname{orb}(1)&=&\{ 2,3\}\\ \operatorname{orb}(2)&=&\{ 1,3\}\\ \operatorname{orb}(3)&=&\{ 1,2\}\\ \end{eqnarray*}
These sets are not disjoint. Hence my doubt.
Then how to proceed to prove second statement.
Any hint or suggestion will be appreciated.
Let $e\in G$ denote the identity element and let $x\in S$. Then by definition of an action you have $e\cdot x=x$, so $x\in\operatorname{orb}(x)$. This is where your supposed counterexample fails. Intuitively speaking; every element can be reached from itself by the action of something in $G$; by doing nothing.
A key step in proving that orbits are disjoint is proving that $$x\in\operatorname{orb}(y)\quad\Leftrightarrow\quad y\in\operatorname{orb}(x).$$ From this it is not hard to show that the relation $\sim$ defined by $$x\sim y\quad\Leftrightarrow\ x\in\operatorname{orb}(y),$$ is an equivalence relation. The equivalence classes partition $S$, and these are precisely the orbits.