The definition of a wellordering is as follows:
If $\prec$ is a partial ordering of a set $X$.
$(X,\prec)$ is a wellordering if
(i) it is a strict total ordering and
(ii) for any subset $Y\subseteq X$, if $Y\neq\varnothing$, then $Y$ has a $\prec$-least element
How is defining $\langle A,R\rangle$ to be a wellordering different to the above definition,
Do these ordered pair brackets change the definition at all, if not why are they there?
The difference is typographical. Somewhat like the difference between $\Bbb R$ and $\bf R$ as the real numbers.
Sometimes people prefer using chevrons for ordered pairs, and sometimes parenthesis. It depends on the context, and the writer.