Difference between real and complex vector spaces.

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Let $V = M_2(\Re)$ be the set of real $2 \times 2$ matrices, with the usual matrix addition and scalar multiplication.

$V$ is an $\Re$-vector space. Why is $V$ not a complex-vector space?

So far, I have thought of verifying whether $V$ satisfies the requirements to be an subspace but don't know where to go next.