Difference between rings and algebras

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It is clear that, if we forget scalar multiplication, associative algebras reduce to rings. It the resulting ring is unital however, one can recover scalar multiplication $ka:=(k1)a$, for all $k\in\mathbb{F}$, the field where the algebra is defined, and $a$ in the algebra. So what is the difference between unital rings and associative unital algebras?

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Notice that to define $ka=(k1)\cdot a$, you have to already know what $k1$ is. If all you have is a ring, then you don't know what $k1$ is yet. The same (unital) ring can have different $\mathbb{F}$-algebra structures, since $k1$ could be defined differently in them.

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The main difference is this: Algebras have a scalar multiplication defined, rings don't. The fact that the multiplication can be recovered to make some rings into algebras in a canonical way is more or less irrelevant.