Let $A, B \in \mathbb R^{n\times n}$ be two positive semidefinite matrices. Assume that $A_{ij}\geq B_{ij}$ for $i,j\in \{1,\dots,n \}$. Does it hold that $C = A - B$ is positive semidefinite?
One possible simplification that I'm also interested in is if $B$ is of rank 1.
The answer is no, even if $B$ has rank $1$. Consider $$A = \begin{bmatrix} 4 & 2 \\ 2 & 1\end{bmatrix} \ge 0, \quad B = \begin{bmatrix} 1 & 1 \\ 1 & 1\end{bmatrix} \ge 0, \quad A-B = \begin{bmatrix} 3 & 1 \\ 1 & 0\end{bmatrix} \not\ge 0.$$