Is a dihedral group only considered for shapes that when reflected or rotated fit exactly back into place of the original image?
My confusion arises from this wikipedia article and specifically from this picture:
Are these symmetries considered a dihedral group?

The dihedral group specifically refers to the symmetries of a regular polygon, so an $n$-gon under any transformation in the dihedral group $D_n$ is mapped to itself. I think the picture in this article is using an $F$ for illustrative purposes, since an $F$ has $no$ symmetry; thus you can see that switching the order of transformations really does make a difference (this would be more difficult to show on an actual square, which is symmetric, so they would need to color the vertices/edges or something like that).