Suppose we have two inner product spaces $V$ and $W$ with dimensions $n$ and $m$, respectively. For some set $\{ \mathbf{v}_i\}_{i=1}^k \in V$ and some nonzero $\mathbf{w} \in W$, where $1 \leq k \leq n$, we let the subspace $U \subset L(V,W)$ be the set of linear maps $T$ between these inner products spaces such that $\langle T \mathbf{v}_i, \mathbf{w} \rangle = 0$.
Now, if that set $\{ \mathbf{v}_i\}_{i=1}^k$ happens to be linearly independent, then what can we say about the dimension of $U$? Is there a range of values that $U$ can take, or is there a unique value? Moreover, I wonder what does it mean, intuitively, for $U$ to have a dimension?
I'm not quite sure where to begin with any of these questions, so any prods in the right direction or heuristic explanations would be helpful.
Firstly, on your question about dimension of $U$: since $L(V,W)$ is a vector space, we can do usual vector space things (finding a basis, finding its dimension, etc.). This of course goes for its subspaces, including $U$.
Now, note that $\langle Tv_i, w \rangle =0$ is equivalent to $T(\text{Span}(\{v_i\}))\subseteq \{w\}^{\perp}$. We are searching for the subspace $U\subset L(V,W)$ of linear maps that send the subspace $\text{Span}(\{v_i\})\subset V$, having dimension $k$, to the subspace $\{w\}^{\perp}\subset W$, having dimension $m-1$. Note that such a map $T$ need not have rank equal to $m-1$, only $<m$; in fact, $T=0$ works fine.
The final steps are not hard, but I'll hide them in case you'd like to do them yourself.
An afterthought (kept in a spoiler):