For an $n\times n$ matrix $A$ over $\Bbb R$, given that $$A^2 = k^2 I_n$$ where $k > 0$, can one prove that $A$ is diagonalizable?
I have a strong feeling about this but I am not really sure as the original question does not explicitly state that this is true.
$\textbf{Case 1:---}$ $k=0$. Then $A^2=0$. Now we can't say, $A$ is diagonalizable. For example consider the matrix $$A:=\begin{bmatrix}0\ 1\\0\ 0\end{bmatrix}.$$ Here $A^2=0$ is zero implies all eigenvalues of $A$ are zero. So if $A$ were diagonalizable then, $A$ would be zero matrix.
$\textbf{Case 2:---}$ $k\not=0$ and $k\in \Bbb R$. In this case $A$ is diagonalizable over $\Bbb R$. As $A$ annihilates the polynomial $(x-k)(x+k)\in \Bbb R[x]$ i.e. minimal polynomial of $A$ is product of distinct linear polynomials.
$\textbf{Case 3:---}$ $k\not\in\Bbb R$ but $k^2\in \Bbb R$. In this case, $A$ annihilates the polynomial $x^2-k^2\in\Bbb R[x]$, and this polynomial does not split over $\Bbb R$. So $A$ can not be diagonalizable over $\Bbb R$ in this case also.
$$\text{ A real matrix is diagonalizable over real numbers}$$ $$\text{if and only if}$$ $$\text{it's minimal polynomial splits as product of distinct linear polynomials with real coefficients.}$$
$\textbf{Edit:---}$ You have assumed $k>0$. So $A$ annihilates the polynomial $(x-k)(x+k)\in \Bbb R[x]$. If there is no non-zero $v\in \Bbb R^n$ with $Av=kv$. Then, $A+kI=0$ as $A-kI$ is invertible. Hence $A$ is scalar matrix.
Similarly if there is no non-zero $v\in \Bbb R^n$ with $Av=-kv$ we can say, $A=kI$.
Next suppose, both $A\pm kI$ are not injective. And write $V=\text{ker}(A-kI)$ and $W=\text{ker}(A+kI)$. Clearly, $V\cap W=\{0\}.$ Also for any $v\in\Bbb R^n$ we have, $$v=\frac{1}{2k}\big(Av+kv\big)-\frac{1}{2k}\big(Av-kv\big),$$$$\frac{1}{2k}\big(Av+kv\big)\in V,$$$$\frac{1}{2k}\big(Av+kv\big)\in W.$$ So that, $V\oplus W=\Bbb R^n$. That is $A$ is diagonalizable.