Let:
- $p_k$ be the $k$th prime
- $p\#$ be the primorial for $p$
- $\pi(x)$ be the prime counting function
From Rosser & Schoenfeld, 1962, for $x \ge 17$:
$$\pi(x) > \frac{x}{\ln x}$$
It seems counterintuitive to me that:
$\pi(p_k\#) > \dfrac{p_{k-1}\#}{3}$
Is the following reasoning valid?
(1) From Rosser 1941 and Dusart 1999 (references here), for $k > 6$:
$$k(\ln(k\ln k)-1)<p_{k}<k{\ln(k\ln k)}\!$$
(2) From $p_k + k > k\ln(k\ln k)$,
$e^{\left(\frac{p_k+k}{k}\right)} > k\ln k$
(3) $2e^{\left(\frac{p_k+k}{k}\right)} > p_k$ since:
$2k\ln k > k\ln k + k\ln(\ln k) = k\ln(k\ln k) > p_k$
(4) For $k \ge 5, 3p_k > \ln p_k\#$ since:
For $k \ge 7, p_k \ge 2k$ since $p_5 = 11 > 2\times 5$; Assume $p_k > 2k$; $p_{k+1} \ge p_k + 2 \ge 2k+2 = 2(k+1)$
$3p_k > 2p_k + 2k > k\ln p_k > \ln (p_k)^k > \ln(p_k\#)$
(5) Thus, for $k \ge 7$, $\pi(p_k\#) > \dfrac{p_k\#}{\ln(p_k\#)} > \dfrac{p_{k-1}\#}{3}$
Your proof is valid, and it is true that $\pi(p_k\#)> p_{k-1}\#/3$. I'm not sure why you think this is counterintuitive?
Asymptotically $p_k\#\approx e^{k\ln(k)}$ and so $\pi(p_k\#)\approx e^{k\ln(k)}/\ln(k\ln k)$. Therefore
$$ \frac{\pi(p_k\#)}{p_{k-1}\#} \approx \frac{e^{k\ln(k/k-1)+\ln(k-1)}}{\ln(k\ln(k))}\gg \frac{k}{\ln(k)} $$
In particular the ratio will $\to \infty$ as $k\to \infty$, so one shouldn't be surprised that it is $>1/3$ even for small $k$.