The two conditions are:
For all unit vectors $\mathbf{x}$ and $\mathbf{y}\hspace{-0.02 in}$, $\:$ if $\; \left|\left|\hspace{.03 in}\mathbf{x}\hspace{-0.05 in}+\hspace{-0.04 in}\mathbf{y}\right|\right| = 2 \;$ then $\: \mathbf{x} = \mathbf{y} \;$.
For all vectors $\mathbf{x}$ and $\mathbf{y}\hspace{-0.02 in}$, $\;$ if $\;\; \left|\left|\hspace{.03 in}\mathbf{x}\hspace{-0.05 in}+\hspace{-0.04 in}\mathbf{y}\right|\right| \: = \: \left|\left|\hspace{.02 in}\mathbf{x}\hspace{.02 in}\right|\right| + \left|\left|\hspace{.02 in}\mathbf{y}\right|\right| \;\;$ then $\mathbf{x}$ and $\mathbf{y}$ are colinear.
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Obviously, the lower of those conditions implies the upper of those conditions.
Does the lower of those conditions follow from the upper of those conditions?
Yes, the first condition implies the second.
Let's prove the contrapositive: If there are linearly independent $x,y$ with $\lVert x+y\rVert = \lVert x\rVert + \lVert y\rVert$, then there are two linearly independent unit vectors $u,v$ with $\lVert u+v\rVert = 2$.
Since the norm is homogeneous, we can assume that $\lVert x\rVert + \lVert y\rVert = 2$. If $\lVert x\rVert = \lVert y\rVert$, we are done. Otherwise, suppose without loss of generality $1-\eta = \lVert x\rVert < \lVert y\rVert = 1+\eta$. Then set $v = \frac{1}{1+\eta}y$ and $u = x + \frac{\eta}{1+\eta}y$. Then $u$ and $v$ are linearly independent (in particular different), $u+v = x+y$, hence $\lVert u+v\rVert = 2$, and $\lVert v\rVert = \frac{1}{1+\eta}\lVert y\rVert = 1$, as well as
$$\lVert u\rVert = \left\lVert x + \frac{\eta}{1+\eta}y\right\rVert \leqslant \lVert x\rVert + \frac{\eta}{1+\eta}\lVert y\rVert = (1-\eta) + \eta = 1,$$
while on the other hand $\lVert u\rVert \geqslant \lVert u+v\rVert - \lVert v\rVert = 2-1=1$, hence also $\lVert u\rVert = 1$.