Does the Cayley–Hamilton theorem work in the opposite direction?

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The Cayley–Hamilton theorem states that every square matrix satisfies its own characteristic equation.

But does it work in the opposite direction?

If for example for a certain matrix $A$ we know that

$ A^2-6A+9I=0, $

does that mean that the characteristic equation of $A$ is

$ \lambda^2-6\lambda+9=0 $ ?

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Even without counterexamples it is obvious that your statement can't be true because if $A$ is a root of the polynomial $p(x)$ then it must be the root of $p(x)q(x)$ for any polynomial $q$. So that way we would get the matrix $A$ has infinitely many characteristic polynomials.

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No, the $n\times n$ matrix $A=3I$ satisfies the given equation but it has a different characteristic polynomial for $n\not=2$.

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No. For example, $I-1=0$, but the characteristic polynomial of $I$ is $(x-1)^n$.

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For any $n \times n$ matrix $A$, the $(2n) \times (2n)$ matrix $\pmatrix{A & 0\cr 0 & A\cr}$ satisfies the characteristic polynomial of $A$, but its own characteristic polynomial is the square of that of $A$.

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No. In general if a matrix is a root of a polynomial, that polynomial is a multiple of the minimal polynomial of that matrix.

Even if you only consider n-degree polynomials for an n×n matrix, this still can fail.

For example, if A=0, then the characteristic polynomial is $x^n$, but A is the root of any polynomial $xg(x)$.

However, all is not lost. If your minimal polynomial equals your characteristic polynomial (as with companion matrices or in the case you have no repeated roots), then the characteristic polynomial (= minimal polynomial) will be the unique monic n-degree polynomial with root A.