In my mind, $\mathbf{R}^{n}$ can look very different from Euclidean space as a metric space, depending on the metric we choose to impose on it. Suppose we have a metric that gives the length of the unit interval in $\mathbf{R}^{n}$ to be $\pi$. Then in this space the Lebesgue measure of the unit interval disagrees with the length given by this different metric. Thus it seems (to me at least) that when we define the Lebesgue measure on $\mathbf{R}^{n}$, which involves giving the unit interval measure $1$, we secretly suppose that we're talking about $\mathbf{R}^{n}$ as the Euclidean space.
But when I look at the full definition of Lebesgue measure, the metric is never mentioned. Only the set-theoretic structure of subsets of $\mathbf{R}^{n}$ is talked about.
In other words, I would only find it reasonable that the set $[0,1]^{p}$ be called the unit $p$-cube if the metric on $\mathbf{R}^{n}$ is Euclidean. But the Lebesgue measure is agnostic about the metric...
Origin of question
I am trying to carefully consider which concepts in multivariate calculus depend on the Euclidean structure, and which do not. For example, differential calculus only involves the affine and topological structure of $\mathbf{R}^{n}$, and can be recast in more general spaces with these properties (Banach space). Vector calculus is largely dependent on the special dimension $n=3$, orientation, and metric.
But what about integration? For example, do the ordinary multiple integrals involve the metric in some way? This question led me to the more general Lebesgue measure, hence this question.
Lebesgue measure on ${\mathbb R}^n$ is defined as product measure resulting from Lebesgue measure on ${\mathbb R}$. The latter is strongly tied to the features present in ${\mathbb R}$: It gives $[0,1]$ the measure $1$, is translation invariant, and behaves as expected under scaling.
It follows that Lebesgue measure in ${\mathbb R}^n$ gives the unit cube $[0,1]^n$ the volume $1$, is translation invariant, and behaves as expected under scaling.
The unit cube is tied to the way ${\mathbb R}^n$ is defined, and can be regarded as the most natural basic set for volume measurement. This cube and its translates, etc., are not affected by any metric you may choose later.
Note that there are different notions of "metric" in this context: (i) a distance function $d:\>{\mathbb R}^n\times {\mathbb R}^n\to{\mathbb R}_{\geq0}$, and (ii) a Riemannian metric defined on some manifold $X$ via a a metric tensor $g$ on the tangent bundle TX.
(i) If you define on the plane ${\mathbb R}^2$ a metric by letting $d(x,y)$ be a somehow established road distance between $x$ and $y$ then the Lebesgue area measurement on ${\mathbb R}^2$ is in now way affected by any roads , sideroads, and capillaries present in the plane.
(ii) The toy example of such a Riemann metric is a constant Riemannian metric on $X:={\mathbb R}^n$ itself. It is given by a positive definite symmetric matrix $[g]=[g_{ik}]$ that has to be provided by you. This metric defines a scalar product $$\langle x,y\rangle:=\sum_{i,k} x_i\, g_{ik}\, y_k$$ on $X$, so that you can do Euclidean geometry on $X$ according to this metric. Now this Euclidean metric on $X$ automatically defines a $d$-dimensional volume for arbitrary $d$-dimensional parallelograms $P\subset X$ via the so-called Gram determinant of the spanning vectors. In particular, the $n$-dimensional $g$-volume of $n$-dimensional parallelotopes $P\subset X$ is a constant multiple of the $n$-dimensional Lebesgue measure $\lambda(P)$; in fact one has $${\rm vol}_g(P)=\sqrt{\det[g]}\>\lambda(P)\ .$$