Let $(V, \cdot, +)$ be a topological vector space over $\mathbb{R}$ or $\mathbb{C}$ with topology $\mathcal{T}$ and let $0 \in V$ be the zero vector. Is then the linear structure $(\cdot, +)$ on the pointed topological space $(V,0)$ uniquely determined by the topology $\mathcal{T}$ and the distinguished zero element $0$?
If not in general, does this hold, if one specifies further requirements on $\mathcal{T}$, i.e. separation axioms?
I don't think so.
Consider $\mathbb{R}$ with the trivial topology. Note that any $\mathbb{R}$-vector space structure on $\mathbb{R}$ makes it into a topological vector space.
Now you can put different vector space structures on $\mathbb{R}$ such that $0$ is the zero vector.
For instance, take a bijection of $\mathbb{R^2}$ onto $\mathbb{R}$ sending $(0,0)$ ont $0$ and consider the induced vector space structure on the codomain obtained from $\mathbb{R}^2$.