I am reading Peter Topping's notes on Ricci flow: on page 99 a statement is made which is needed for his proof of a version of Perelman's no local volume collapse theorem, but I am not sure why it holds. If you define $\omega_n$ to be the volume of the unit ball in Euclidean $n$-space and $V(p,s)$ to be the volume of the geodesic ball at point $p$ with radius $s$ given a complete Riemannian manifold $(M,g)$, then he argues that the volume ratio always tends to the volume of the Euclidean unit ball. $g(t)$ is a Ricci flow on the manifold for $t \in [0,T]$ and we are working with a smooth metric $g(T)$.
$K(p,s)=\frac{V(p,s)}{s^{n}} \rightarrow \omega_n$
as $s \rightarrow 0$. I am not sure why this would have to hold on an arbitrary complete Riemannian manifold. If you are working on hyperbolic space or something like that with negative curvature, then now surely that relation will not hold as you will have a $\sinh$ term in the denominator meaning that the ratio would tend to $0$, as opposed to the volume of the Euclidean unit ball.
Let $B^n$ denote the unit ball in $T_pM$. For $s>0$ small, let $\varphi_s:B^n\hookrightarrow M$ be given by $$v\mapsto\exp_p(sv).$$ Let $g_s$ be the pull-back metric on $B^n$ with respect to $\varphi_s$, that is, $g_s=\varphi_s^*g.$ Then, by definition, the volume $V(p,s)$ is equal to the volume of $B^n$ with respect to the metric $g_s$. It follows that the volume ratio, $K(p,s)$, is equal to the volume of $B^n$ with respect to the metric $h_s:=\frac{g_s}{s^2}.$ A short computation shows that, as $s$ goes to $0$, the metric $h_s$ converges (uniformly) to the constant metric $$(h_0)_q(u,v)=g_p(u,v),\qquad q\in B^n,u,v\in T_pM.$$ Hence, the corresponding Riemannian volume forms converge to the standard volume form and the claim follows.
Edit: Let us write the metric $g_s$ explicitly: for $q\in B^n$ and $u,v\in T_pM$ we have $$\begin{align}(g_s)_q(u,v)&=g_{\exp_p(sq)}(d(\exp_p)_{sq}(su),d(\exp_p)_{sq}(sv))\\&=s^2g_{\exp_p(sq)}(d(\exp_p)_{sq}(u),d(\exp_p)_{sq}(v)).\end{align}$$ The metric $h_s$ is thus given by $$(h_s)_q(u,v)=g_{\exp_p(sq)}(d(\exp_p)_{sq}(u),d(\exp_p)_{sq}(v)).$$By continuity of $g$, we have $$\begin{align}\lim_{s\to0}(h_s)_q(u,v)&=g_{\exp_p(0)}(d(\exp_p)_0(u),d(\exp_p)_0(v))\\&=g_p(u,v),\end{align}$$ where the convergence is uniform.