The PSD cone is the set of all positive semidefinite matrices. The dual is the set of all matrices $A$ such that tr($A^T X$) $\geq 0$ for all positive semidefinite matrices $X$.
How to prove that the PSD cone is self-dual,i.e. the dual is also the set of all positive semidefinite matrices?
First note that a symmetric matrix $X\in \mathbb S^n$ is PSD if and only if it is a sum of outer products $X = \sum_{i=1}^n x_i x_i^T$ (proof via cholesky). By definition (using the fact that $\operatorname{tr}(A^TX)=\langle A, X\rangle$ is the natural inner product (Frobenius) on $\mathbb S^n$):
Then
So in essence it boils down to the equivalence
$$ \langle X, uu^T\rangle\ge 0\forall u\in\mathbb R^n\iff \sum_{i=1}^N\langle X, u_iu^T_i\rangle\ge 0\forall u_i\in\mathbb R^n $$