$A$ is a 3x3 symmetric matrix. You know that $2$ and $5$ are eigenvalues of $A$, and
$$V_5 = Span \left( \begin{pmatrix} 1 \\ 2 \\ 0 \end{pmatrix} ,\begin{pmatrix} 1 \\ 1 \\ 1 \end{pmatrix} \right) $$
is the eigenspace of the eigenvalue $5$. Which of the following statements is true?
(1) $$V_2 = Span \begin{pmatrix} 2 \\ -1 \\ -1 \end{pmatrix} $$
(2) $A$ is diagonalizable.
(3) There aren't three eigenvectors of $A$ orthogonal between them.
(4) $$ V_2 = \left\{ \begin{pmatrix} x \\ y \\ z \end{pmatrix} | x + y + z = 0 \right\} $$
How can I find the true statement(s)?
You know that $A$ is a square symmetric matrix. So, from the Spectral Theorem:
From that you have the following:
This means that $V_\alpha \bot V_\beta$ for every autovalue $\alpha \neq \beta$.
From the previous you know that option (3) is false.
You can find the cartesian equation of $V_5$:
$$2x - y - z = 0$$
and the parametric equation of $V_{2_1}$:
$$ \begin{cases} x = 2 \alpha \\ y = -\alpha \\ z = -\alpha \end{cases} $$
So:
$$n[V_5] = d[V_{2_1}] = \begin{pmatrix}2 \\ -1 \\ -1 \end{pmatrix}$$
This means that $V_{2_1} \bot V_5$, so option (1) is true.
Option (4) is false because:
$$n[V_5] = \begin{pmatrix}2 \\ -1 \\ -1 \end{pmatrix} \neq d[V_{2_4}] = \begin{pmatrix}1 \\ 1 \\ 1 \end{pmatrix}$$
Option (2) is true because: $A$ is symmetric $\implies$ $A$ is diagonalizable