In trying to prove that the number of spanning trees in $K_5$ is $125$ I adopted the following method:
Let $S$ be the set of all such spanning trees and let $S_5$ act in a natural way on $S$. Now exactly three nonisomorphic spanning trees $T_1=K_{1,4},T_2=P_5,T_3=\text{chair}$ are possible with $\text{Stab}(T_i)=\text{Aut}(T_i)$.
As $|\text{Orbit}(T_i)|=\frac{|S_5|}{|\text{Stab}(T_i)|}$ and as $S$ is a disjoint union of the three orbits so we have: $$|S|=\frac{5!}{4!}+\frac{5!}{2!}+\frac{5!}{2!}=125.$$
This result can be obtained purely by counting arguments as well, but I find the above proof more satisfying. What are some other elementary counting proofs in combinatorics which can be interpreted in terms of group action?
Here is another example of the type of results that I am looking for:
The number of ways of choosing $k$ distinct objects out of $n$ where the order matters is $\frac{n!}{(n-k)!}$.
Proof: Suppose $G=S_n$ and $X=\cup_{m=1}^n \{(x_1,\ldots,x_m):x_i\ne x_j\text{ for }i\ne j, x_i\in[n]\}$. The function from $G\times X$ to $X$ defined by $\sigma\cdot (x_1,\ldots,x_m)=(\sigma(x_1),\ldots,\sigma(x_m))$ is clearly a group action.
Let $x=(x_1,\ldots,x_k)\in X$. Then $\mathcal{O}_x$ is precisely the collection of all $k$-tuples from $[n]$ where each coordinate is different. Our proof will be finished if we show that $|\mathcal{O}_x|=\frac{n!}{(n-k)!}$. Note that the permutations which fix $x$ and thereby each $x_i$ are exactly those which permute elements other then $x_1,\ldots,x_k$ and such permutations are precisely $(n-k)!$ in number. So $|G_x|=(n-k)!$. The result now follows by invoking the orbit stabilizer theorem.
A similar result $\tbinom{n}{k}=\frac{n!}{k!(n-k)!}$ can be obtained by letting $X$ to be the set of all $k$-subsets of $[n]$.
There are counting-proof methods for this, but here's the group action proof using Burnside's Lemma:
It is obvious that there are $\binom{16}{8}=12870$ different ways to color the board. To make this interesting, instead suppose that colorings are considered the same if they map to each other using rotations and reflections.
Let $G=\{ e,A,B,C,D,90^\circ,180^\circ,270^\circ\}$ be the group of symmetries where $A$ and $B$ are vertical and horizontal reflections, $C$ and $D$ are diagonal reflections, and $90^\circ,180^\circ,270^\circ$ are the rotations. Then: $$|S^e|=\binom{16}{8}$$ $A$ and $B$ reflect halves, so: $$|S^A|=|S^B|=\binom{8}{4}$$ Since $90^\circ$ and $270^\circ$ project to each quadrant, we get $$|S^{90^\circ}|=|S^{270^\circ}|=\binom{4}{2}$$ Similarly, $180^\circ$ exchanges halves: $$|S^{180^\circ}|=\binom{8}{4}$$ For $C$ and $D$, there are either 0, 2, or 4 black squares along the diagonal. Otherwise, we would reach a contradiction as an odd number of black squares must be split evenly into two halves. Case 1: No black squares on the diagonal. This means there are 4 black squares taking up 6 squares on each half. This gives $\binom{6}{4}$. Case 2: 2 black squares on diagonal. In this case, we have 6 squares left which are split into 3 per half (out of 6 available squares), so we have $\binom{6}{3}$. But there are $\binom{4}{2}$ different ways of arranging the black squares on the diagonal. Thus, for Case 2 we have $\binom{6}{3}\binom{4}{2}$. For Case 3 (4 black squares on diagonal), each side has 6 total squares and 2 black squares, which is $\binom{6}{2}$. Combining the cases, we get: $$|S^C|=|S^D|=\binom{6}{4}+\binom{6}{3}\binom{4}{2}+\binom{6}{2}$$ Applying Burnside's Lemma, $$|S/G|=\frac{1}{|G|}\sum_{g\in G}|S^g|=\frac{1}{8}\left[\binom{16}{8}+3\binom{8}{4}+2\binom{4}{2}+ 2\left[\binom{6}{4}+\binom{6}{3}\binom{4}{2}+\binom{6}{2}\right] \right]$$$$=1674.$$