I am wondering if there is a simple example of a manifold such that, given a value for the scalar curvature $R$, I can find a manifold such that the Ricci tensor has all zero components except for one component which takes the value $R$.
I know this could be achieved using a warped product of two metrics to separate out one coordinate and then solve the differential equations so that the first coefficient vanishes, but obviously the coefficient of the non-zero component needs to be $R$.
Here's a reasonably explicit construction, similar to the one in my answer to your related question, that works in some cases, namely when $R$ is strictly positive and we work in a neighborhood of any point not critical for $R$. The latter condition guarantees that there are coordinates $(x_1, \ldots, x_{n - 1}, y)$ for which $R$ is a function of $y$ alone.
If we take $\bar g := \sum_{i = 1}^{n - 1} dx^i \otimes dx^i$ (the standard Euclidean metric on $\Bbb R^{n - 1}$) and $dy^2$ to be the standard metric on $\Bbb R$, then the Ricci tensor of $$g := F(y) \bar g + G(y) dy^2$$ is $$\operatorname{Ric} = \frac{2 F'' F G - F' G' F + (n - 3) (F')^2 G}{4 F G^2} \bar g - \frac{3 (2 F'' - (F')^2 G - F' G' F)}{F^2 G} dy^2 .$$
We want this to coincide with $R \,dy^2$ for some scalar function $R$, which amounts to asking (1) that the coefficient of $\bar g$ vanish and (2) the coefficient of $dy^2$ be our prescribed function $R$.
This is a nonlinear system of two o.d.e.s in unknown functions $F, G$, but we can still solve it as explicitly as one might hope. The solutions are given by $$F(y) = C \exp \left[\pm \frac{2}{\sqrt{(n - 1) (n - 2)}} \int_{y_0}^y \sqrt{R(t)} \,dt\right], \quad G(y) = C F'(y)^2 F(y)^{n - 3}, \quad C \in \Bbb R,$$ and this defines a metric if $C > 0$.