I saw this on Wikipedia about the hierarchy of spaces:

Later in the article, it states that the fundamental building blocks of mathematical spaces are vector spaces and topological spaces. However, it's not clear to me how topological spaces and vector spaces are related, if at all.
Can someone provide an example of a vector space that is not a topological space and vice versa?
Vector spaces and topological spaces are fundamentally different concepts; one is a set with and addition and scalar multiplication, the other a set together with a set of subsets (the open sets) with certain constraints.