There are a lot of interesting and creative examples of categories, such as for example, the category whose objects are the positive integers and the set of morphisms from $n$ to $m$ is the set of $m \times n$ matrices with values in some ring with identity $R$.
Therefore, my question is: are there some nice (creative) examples of additive categories? In this case, could you describe their structures?
I would be grateful for some references on this.
The best ones, in my experience, are the ones that are also Abelian categories, so I'd make sure these make it onto your list.
For example, the category of Abelian groups and Abelian group homomorphisms, but also the category of left (resp. right) $R$-modules and left (resp. right) $R$-module homomorphisms for a fixed ring $R$. These are the most important examples in my opinion, as additive categories are usually introduced to build to Abelian categories, of which these are the most important (they are used very often in homological algebra).