Given an operator $\hat{\alpha}$, how do we obtain,
$$ \sqrt{ \left\langle \left( \hat{\alpha} - \left\langle\hat{\alpha}\right\rangle \right)^2 \right\rangle } = \sqrt{ \left\langle\hat{\alpha}^2\right\rangle - \left\langle\hat{\alpha}\right\rangle^2 } $$ My thoughts... To simplify, I define $A$ as,
$$ A\equiv \left( \hat{\alpha} - \left\langle\hat{\alpha}\right\rangle \right)^2 = \hat{\alpha}^2 + \left\langle\hat{\alpha}\right\rangle^2 - 2\hat{\alpha}\left\langle\hat{\alpha}\right\rangle $$ so what do I do with the extra $-2 \left\langle \hat{\alpha}\left\langle\hat{\alpha}\right\rangle \right\rangle$ in $\langle A\rangle$?
$$ \implies \left\langle \hat{\alpha}^2 \right\rangle + \left\langle \left\langle\hat{\alpha}\right\rangle^2 \right\rangle -2 \left\langle \hat{\alpha}\left\langle\hat{\alpha}\right\rangle \right\rangle $$
$$ -2 \left\langle \hat{\alpha}\left\langle\hat{\alpha}\right\rangle \right\rangle = -2 \left\langle \hat{\alpha} \right\rangle \left\langle\hat{\alpha}\right\rangle $$ and that is true because the $\langle \ \ \rangle $ "sees" $\hat{\alpha}$, since $\langle \hat{\alpha} \rangle $ has already been acted upon, and thus, is a number. In general, this is complex and in the case of hermitian $\hat{\alpha}$, real. So, we get,
$$ \left\langle \hat{\alpha}^2 \right\rangle + \left\langle \left\langle\hat{\alpha}\right\rangle^2 \right\rangle -2 \left\langle \hat{\alpha}\left\langle\hat{\alpha}\right\rangle \right\rangle = \left\langle \hat{\alpha}^2 \right\rangle + \left\langle\hat{\alpha}\right\rangle^2 -2 \left\langle \hat{\alpha} \right\rangle^2 = \left\langle \hat{\alpha}^2 \right\rangle - \left\langle\hat{\alpha}\right\rangle^2 $$ and the rest follows.