Consider a bilinear form $f(A,B) = n\operatorname{Tr}(AB) - \operatorname{Tr}(A)\operatorname{Tr}(B)$ defined on $M_n(\mathbb{C})$.
I need to find the set $U^\perp$ of all matrices $A$ such that $f(A,B) = 0$ for every $B \in M_n(\mathbb{C})$, or, more specifically, find $\dim(U^\perp)$.
Other than the zero matrix I can't find any other general matrix. So $\dim (U^\perp) = 0$ I'd assume?
I know that this is no complete answer, but just a hint that you might not have found all matrices such that $f(A,B) = 0 ~ \forall B$:
Take $c \in \mathbb{C}$ to be any complex number and let $I$ be the $n \times n$ identity matrix. Then $$Tr(c \cdot I) = n \cdot c$$ and $$Tr(c \cdot I \cdot B) = Tr(c \cdot B) = c \cdot Tr(B)$$ Hence, $$f(c \cdot I, B) = n \cdot c \cdot Tr(B) - n \cdot c \cdot Tr(B) = 0$$