So I've got the answer as $r=5$. Here's how I got it.
$$T(r) = \binom{14}{r}\cdot(5)^{14-r}\cdot(2x)^r$$
$$T(r+1) = \binom{14}{r+1}\cdot(5)^{13-r}\cdot(2x)^{r+1}$$
$$T(r+1)/T(r) > 1$$
$$r > 4.21$$
So that $$r=5$$
My question is why can't we take $r=6$ or $r=7$?
I prefer to go the other way.
$$T_r = \binom{14}{r}5^r \left[ ~\frac{8}{3} ~\right]^{14-r}.$$
As $~r~$ goes from $~0~$ to $~7,~$ you have that $~\displaystyle \binom{14}{r}~$ is strictly increasing. Then, since $~5 > \dfrac{8}{3}~$ you must have that $~T_r~$ is strictly increasing.
So, the optimal value of $~r~$ must be $~\geq 7.~$
For $~r \in \{7,8,\cdots,13\}~$ you have that
$$\frac{\binom{14}{r+1}}{\binom{14}{r}} = \frac{14-r}{r+1}.$$
Therefore, for $~r \in \{7,8,\cdots,13\},~$ you have that
$$\frac{T_{r+1}}{T_r} = \frac{14-r}{r+1} \times \frac{5}{(8/3)} = \frac{14-r}{r+1} \times \frac{15}{8}.$$
For $~r \in \{7,\cdots,13\},~$
Let $~f(r)~$ denote $~\dfrac{T_{r+1}}{T_r}.$
Let $~g(r)~$ denote $~\dfrac{T_r}{T_7}.$
This implies that for $~r \geq 8,~$ that
$g(r) = f(7) \times f(8) \times \cdots \times f(r-1).$
The goal is to maximize $~g(r).$
Then:
$\displaystyle f(7) = \frac{7}{8} \times \frac{15}{8} > 1.$
$\displaystyle f(8) = \frac{6}{9} \times \frac{15}{8} = \frac{90}{72} > 1.$
$\displaystyle f(9) = \frac{5}{10} \times \frac{15}{8} = \frac{75}{80} < 1.$
At this point, the analysis can stop, because for $~r \in \{9,10,11,12,13\},~$ the fraction $~\dfrac{14-r}{r+1}~$ is strictly decreasing.
Therefore, you have that $~f(7) > 1, ~f(8) > 1,~$ and $f(r) < 1 ~: ~r \in \{9,10,11,12,13\}.$
Therefore, $~g(r)~$ is maximized at $~g(9) = f(7) \times f(8).$
Therefore, $~T_9~$ is the maximum coefficient.
Noting that my definition of $~T_9~$ is equivalent to the original poster's definition of $~T(5),~$ my answer agrees with the original poster's answer.