Let $S$ is subspace of $\mathbb R^4$ and $L((1,2,2,3),(1,3,3,2))=S$
a) Find one base of subspace $S^{\bot}$
b) Finding that base is the same finding solution for $Ax=0$ but for which matrix?
a) It is easy I find a base $L((-5,1,0,1),(0,-1,1,0))$
b) For matrix which $\ker(A)=L((-5,1,0,1),(0,-1,1,0))$ and they are orthogonal to every member of row space of matrix $A$. Is this the full answer?
We have $$\begin{bmatrix} 1 & 2 & 2 & 3 \\ 1 & 3 & 3 & 2\end{bmatrix} \sim \begin{bmatrix} 1 & 2 & 2 & 3 \\ 0 & 1 & 1 & -1\end{bmatrix} \sim \begin{bmatrix} 1 & 0 & 0 & 5 \\ 0 & 1 & 1 & -1\end{bmatrix}$$
so the basis for $S^\perp$ is $\{(0,-1,1,0), (-5,1,0,1)\}$, as you said.
To find $S^\perp$ we can solve $Ax = 0$ if and only if the matrix $A$ satisfies $\ker A = S^\perp$, or equivalently $R(A^T) = S$. Therefore the rows of $A$ must span $S$.