Let $Q$ be the quiver:
$$\begin{array}{ccccc} & & \\ 1 & \rightrightarrows & 2 & \rightrightarrows &3 & \end{array}$$
I want to find all simple modules over the complex path algebra of $Q$.
In class we defined the category $Q\textbf{-Mod}$ of modules $M$ over a quiver $Q$. Where $Q\textbf{-Mod} \ni M$ consists of vector spaces $M_i$ for every vertex $i \in Q_0$ and $k$-linear maps $M(\alpha) \colon M(i) \to M(j)$ for every $\alpha \in Q_1$ with morphisms between any two such modules $M,N$: $\phi \colon M\to N$ is a collection $\{\phi_i\}_{i\in Q_0}, \phi_i \colon M(i) \to N(i)$ such that the obvious square commutes. We also proved that we have a bijection between $Q\textbf{-Mod}$ and $K[Q]\textbf{-Mod}$, the category of modules over the path algebra of $Q$ over $K$.
Since we have this bijection (which I believe actually gives us equivalence of categories?) we can work with $Q\textbf{-Mod}$ instead of $K[Q]\textbf{-Mod}$, right?
Then $M\in Q\textbf{-Mod}$ is said to be simple if its only submodules are $M$ and $0$. So if the dimension of the direct sum $\bigoplus_{i\in Q_0} M(i)$ is equal $1$ then $M$ must be simple so I think that
$$\begin{array}{ccccc} & & \\ \mathbb{C} & \rightrightarrows & 0 & \rightrightarrows &0 & \end{array}$$
$$\begin{array}{ccccc} & & \\ 0 & \rightrightarrows & \mathbb{C} & \rightrightarrows &0 & \end{array}$$
$$\begin{array}{ccccc} & & \\ 0 & \rightrightarrows & 0 & \rightrightarrows & \mathbb{C} & \end{array}$$
are all simple. But are there any other such simple modules? Or rather is this even correct? It looks too simple. To be honest I find this very hard and confusing. Is it better to work directly with modules over $\mathbb{C}[Q]$ instead?
If your quiver $Q$ has no oriented cycles (and only in this case), then it is true that the simple representations of $Q$ are exactly the one-dimensional representations of $Q$ (so there is exactly one for every vertex of $Q$).
One way to see this is to use Nakayama's lemma: Let $R$ be a unital (not necessarily commutative) ring, and let $J$ be its Jacobson radical. If $M$ is a finitely-generated right $R$-module, then $M\cdot J$ is a proper submodule of $M$.
Now, let $M$ be a simple $\mathbb{C}[Q]$-module (this implies that $M$ is finitely-generated). The Jacobson radical $J$ of $\mathbb{C}[Q]$ is the two-sided ideal generated by the arrows of $Q$. Since $M\cdot J$ is a proper submodule of $M$ (by Nakayama's lemma) and $M$ is simple, we must have $M\cdot J = 0$. In other words, the action of all the arrows of $Q$ on $M$ is the zero action.
This means that in the $Q$-representation corresponding to $M$, all the linear maps attached to arrows of $Q$ are zero maps. In this case, the only way for $M$ to be simple is to be one-dimensional.
Some comments:
Indeed, it is an equivalence of categories.
It depends on the situation. The best is to know both categories.